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# Distillation and chromatography

Year 7 Chemistry · Pure substances and mixtures

<!-- Speaker note: Students describe the principles of distillation and chromatography, identify a mixture for each, and explain when distillation is chosen over evaporation (AC9S7U06, node 4). About 25 minutes (Engage and Explore 10 min · Explain 8 min · Evaluate 3 min · Typical adds 4 min, Wider about 15 min). -->

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## Today

**We are learning to** distillation collects a liquid by boiling and condensing it; chromatography separates dissolved substances such as dyes. Explain each principle and when distillation beats evaporation.

- I can describe the principle of distillation and of chromatography.
- I can name a mixture each technique suits.
- I can explain when distillation is used instead of evaporation.

<!-- Speaker note: Before class: A concept tutorial for introducing or revising the techniques. Set the width with `?width=minimum`, `typical` (default) or `wider`. The node's response mode is structured reasoning: students confuse distillation with evaporation because both heat a liquid. The Explain sort scaffolds the comparison row by row. First Nations content: the node file lists steam distilling among First Nations techniques. This tutorial does not claim that. It presents documented traditional tea tree use (crushing and soaking leaves) and makes clear that steam distillation is the modern extraction method. Check with local community knowledge and protocols, and adapt to the Country your school is on. -->

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## Why it matters

> Ships at sea make fresh water by boiling seawater and catching the steam. Forensic scientists find out which pen wrote a note by letting water creep up a strip of paper.

<!-- Speaker note: Two more techniques. Distillation uses the same property as evaporation (boiling point) but keeps the vapour. Chromatography separates substances that are **all** dissolved. -->

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## Engage: predict

**Seawater is heated in a flask. A tube carries the steam through a cold jacket into a second, empty flask. What collects in the second flask?**

- Nothing
- Salty water
- Fresh water
- Salt

<!-- Speaker note: What happens: Fresh water. Only water particles boil off; the salt stays behind in the first flask. Take two or three predictions before anyone runs it. -->

<!-- Speaker note: Teacher: most students predict salty water. Watch the board together to see only water particles cross. -->

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## Explore it

{{embed: https://studio.learningwaypoints.com/tutorials/_playground-science/index.html?id=deck%2Fscience%2Fchemistry%2Fdistil-chroma%2Fstep-2&code=widget%3A+distil%0A}}

[Open this step in the tutorial](https://studio.learningwaypoints.com/tutorials/science/chemistry/distil-chroma/?full=step-2#step-2)

<!-- Speaker note:  -->

<!-- Speaker note: Teacher: chromatography is quick to run for real with felt-tip pens, filter paper and water; do it if you can. -->

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## What happened?

* Fresh water. Only water particles boil off; the salt stays behind in the first flask.

<!-- Speaker note: Reveal after running. Ask who predicted it, and what made them think so. -->

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## Compare

**Both techniques heat a liquid until it turns to gas. Sort each statement.**

Groups: Evaporation only · Distillation only · Both

Uses the difference in boiling point · Needs heat · The vapour escapes into the air · The vapour is cooled and collected as a liquid · You end up with only the solid · You end up with the liquid and the solid · Needs a condenser and a collecting flask

* Answer: Uses the difference in boiling point → Both; Needs heat → Both; The vapour escapes into the air → Evaporation only; The vapour is cooled and collected as a liquid → Distillation only; You end up with only the solid → Evaporation only; You end up with the liquid and the solid → Distillation only; Needs a condenser and a collecting flask → Distillation only

<!-- Speaker note: Same property, different outcome: distillation keeps the vapour by cooling it. -->

<!-- Speaker note: Teacher: read the sort aloud as a comparison table: same property, different outcome, different equipment. -->

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## The dyes

**Why do the dyes in the ink end up at different heights?**

- The dyes evaporate at different speeds
- Heavier dyes sink lower
- The water makes new colours as it rises
- Each dye dissolves in the water and sticks to the paper differently, so the water carries each one a different distance

* Answer: Each dye dissolves in the water and sticks to the paper differently, so the water carries each one a different distance

<!-- Speaker note: Dyes that dissolve well and stick weakly travel furthest. -->

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## Which technique suits?

**Match each job to the technique that suits it.**

| | |
|---|---|
| `Get drinking water from seawater` | A. Evaporation |
| `Get salt from seawater, letting the water go` | B. Distillation |
| `Find out which dyes are in a black ink` | C. Chromatography |
| `Get sand out of sandy water` | D. Filtration |

* Answer: Get drinking water from seawater → B. Distillation; Get salt from seawater, letting the water go → A. Evaporation; Find out which dyes are in a black ink → C. Chromatography; Get sand out of sandy water → D. Filtration

<!-- Speaker note: Need the liquid back? Distil. Need only the dissolved solid? Evaporate. Several dissolved substances, such as dyes? Chromatography. -->

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## Mix it up

**Looking back at heating curves: water in a flask is boiling and the heat stays on full. What does a thermometer in the water show over the next few minutes?**

- It goes up and down
- It drops, because the water is turning to steam
- It stays at about 100 °C
- It keeps rising

* Answer: It stays at about 100 °C

<!-- Speaker note: During a change of state the temperature stays the same: the energy goes into pulling the particles apart into steam. What this step is for: The flat part of a heating curve explains why boiling water holds a steady temperature, which is what the flask in a distillation is doing. -->

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## Elaborate: distillation or evaporation?

**Both use the same property. Which would you choose?**

Groups: Evaporation · Distillation

A salt farm wants salt from seawater. · A ship needs drinking water from seawater. · A lab wants very pure water with nothing dissolved in it. · You want sugar crystals from sugar syrup. · You want to keep both the water and the salt from a salt solution.

* Answer: A salt farm wants salt from seawater. → Evaporation; A ship needs drinking water from seawater. → Distillation; A lab wants very pure water with nothing dissolved in it. → Distillation; You want sugar crystals from sugar syrup. → Evaporation; You want to keep both the water and the salt from a salt solution. → Distillation

<!-- Speaker note: Ask: do I need the liquid? If yes, distil. What this step is for: The choice depends on what you want to keep: if you need the liquid, distil. -->

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## Elaborate: three techniques, three properties

**Which property does each technique use?**

Groups: Boiling point · How well each substance dissolves and sticks to the paper · How much solid can stay dissolved

Crystallisation: a hot, concentrated solution is left to cool, and crystals form. · Chromatography: food colourings separate on paper. · Distillation: alcohol is separated from water.

* Answer: Crystallisation: a hot, concentrated solution is left to cool, and crystals form. → How much solid can stay dissolved; Chromatography: food colourings separate on paper. → How well each substance dissolves and sticks to the paper; Distillation: alcohol is separated from water. → Boiling point

<!-- Speaker note: What this step is for: Crystallisation, chromatography and distillation each use a different property. -->

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## Elaborate: First Nations knowledge and plant oils

**Which property or process does each step use?**

Groups: Breaking up the leaves so substances can get out · Some substances dissolve in water · The oil is carried away with steam, then condensed · The oil floats on the water

Crushing tea tree leaves · Soaking crushed leaves in water · Modern steam distillation: steam passes through the leaves · Modern steam distillation: separating the collected liquid

* Answer: Crushing tea tree leaves → Breaking up the leaves so substances can get out; Soaking crushed leaves in water → Some substances dissolve in water; Modern steam distillation: steam passes through the leaves → The oil is carried away with steam, then condensed; Modern steam distillation: separating the collected liquid → The oil floats on the water

<!-- Speaker note: What this step is for: Traditional and modern methods of getting substances out of plants both rely on property differences. -->

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## Blue

**The blue spot moved 8.0 cm. What is its Rf value?**

* Answer: 0.8

<!-- Speaker note: 8.0 ÷ 10.0 = 0.80 -->

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## Red

**The red spot moved 5.0 cm. What is its Rf value?**

* Answer: 0.5

<!-- Speaker note: 5.0 ÷ 10.0 = 0.50 -->

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## Unknown dye

**An unknown dye has Rf = 0.50 in the same setup. Which dye could it be?**

- The red dye
- The blue dye
- None of them

* Answer: The red dye

<!-- Speaker note: Same Rf value, same conditions: probably the same substance. -->

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## One spot

**A green ink gives just one spot. What can you conclude?**

- It is definitely a pure substance
- The test failed
- It is probably one dye, but two dyes with the same Rf value would also give one spot

* Answer: It is probably one dye, but two dyes with the same Rf value would also give one spot

<!-- Speaker note: Testing again with a different solvent would check. -->

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## Evaluate: look back

What did you think would collect in the second flask? Write one sentence: "At first I thought… Now I think… because…"

**Revision summary**

- Distillation separates a liquid from what is dissolved in it by boiling the liquid and cooling the vapour back into a liquid somewhere else.
- Evaporation and distillation use the same property (boiling point), but distillation collects the vapour and evaporation lets it escape.
- Chromatography separates a mixture of dissolved substances, such as dyes, because each is carried a different distance.
- Distillation suits seawater (to get water). Chromatography suits inks, food colourings and plant pigments.

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## Exit ticket

**Why would a ship use distillation, not evaporation, to get drinking water from seawater?**

* Distillation collects the water vapour as liquid; evaporation lets it escape and keeps only the salt.

<!-- Speaker note: Students answer on paper or a mini whiteboard before the reveal. Anyone who cannot answer needs the main idea again next lesson. Where this leads: Next in class: AC9S7U06 node 5, choosing and justifying a technique for a new mixture, works best as a class task. Practical: paper chromatography of felt-tip pens or food colourings; a demonstration distillation of coloured water. -->
